基本信息:
赵学波,男,1965年生,辽宁桓仁人,博士,教授,博士生导师。
E-mail: zhaoxuebo@qlu.edu.cn
个人主页:zhaoxuebo.polymer.cn
简介
赵学波,齐鲁工业大学(山东省科学院)材料学部教授、博导、氢电能源材料团队负责人。中国科学院“百人计划”获得者,山东省“泰山学者”特聘专家,山东省氢能源与燃料电池产业联盟专家,中国能源学会专家委员会新能源组副主任专家委员。在国际著名学术期刊Science、Nature-Chemistry、Nature-Communications、JACS、Angew、Advanced Materials、Advanced Functional Materials、Nano Energy、ACS Nano、Applied Catalysis B: Environmental、Chemistry of Meterials、Journal of materials chemistry A、Chemical Communications等学术期刊上发表100余篇SCI收录的研究论文,被国内外同行引用8000多次,最高单篇引用1200多次。主持国家自然科学基金、山东省“泰山学者”资助项目、中国科学院知识创新工程重要方向项目等国家级及省部级科研项目十余项。2016、2017连续两年入选英国皇家化学会Top 1% 高被引中国作者榜单,2021年入选爱思唯尔“中国高被引学者”榜单(化学工程与技术93/172)。赵教授1986年毕业于抚顺石油学院石化系(现辽宁石化大学)并留校任教,1993年获中国石油大学硕士学位。2000年英方全奖出国留学,2005年获英国纽卡斯尔(Newcastle)大学博士学位并留在该校继续从事研究工作。留英期间获“国家优秀自费留学生奖”和英国燃烧工程协会杰出研究成就奖“The Derek Ezra Award 2004”,2010年全职回国工作。他现在负责的科研团队现有6名正式成员(教授2人,副教授3人,讲师1人)和11
博士硕士研究生,主要从事新型金属有机框架材料(MOFs)、新型碳材料的制备及其在氢能、气体分离与存储、新型电极材料、储能材料的研究工作。
主要科研项目:
1.“基于“定向附着晶化”机理的无缺陷MOF膜的构建及其气体分离性能研究”,国家自然科学基金面上项目,66万元,在研
2.齐鲁工业大学高层次人才引进项目,1200万,在研
3.“PEM电解水制氢非贵金属碳纳米管催化层/扩散层一体化膜电极的研制”,济南市“新高校20条”项目,120万,在研
4.“MOF碳基功能材料的制备与应用研究”,山东省“泰山学者”资助项目,200万元,结题
5.“六元氮杂环类MOF碳化制备氮掺杂有序微孔活性碳的规律及其性能研究”,国家自然科学基金面上项目,95万元,结题
6.“温和条件下基于Kubas键的氢分子非解离化学吸附储氢研究”,61万元,结题
7.“氢/氘分子在微孔碳材料上的动力学量子筛分离机理的研究”,国家自然科学基金面上项目,37万元,结题
8.“纳孔金属有机化合物氢气分子吸附机制及扩散特性研究”,中国科学院知识创新工程重要方向项目,200万元,结题
9.中国科学院国防科技创新基金项目,60万元,结题
10.“新型微孔储能材料研究”,所长创新基金项目,70万元,结题
代表性论文:
第一作者代表论文:
1. Hysteretic Adsorption and Desorption of Hydrogen by Nanoporous Metal-Organic Frameworks, Xuebo Zhao, Bo Xiao, Ashleigh J. Fletcher, K. Mark Thomas*, Darren Bradshaw, Matthew J. Rosseinsky*, Science, 2004, 306, 1012-1015.
2. Hydrogen Adsorption on Functionalized Nanoporous Activated Carbons, X. B. Zhao, B. Xiao, A. J. Fletcher and K. M. Thomas*, J. Phys. Chem. B, 2005, 109, 8880-8088.
3. Kinetic Isotope Effect for H2 and D2 Quantum Molecular Sieving in Adsorption/ Desorption on Nanoporous Carbons, Xuebo Zhao, S. Villar-Rodil, A. J. Fletcher, K. M. Thomas*, J. Phys. Chem. B, 2006, 110, 9947-9955.
4. Kinetic molecular sieving, thermodynamic and structural aspects of gas/vapor sorption on metal organic framework [Ni-1.5(4,4'-bipyridine)(1.5)(H3L)(H2O)(3)][H2O](7) where H6L=2,4,6-trimethylbenzene-1,3,5-triyl tris(methylene)triphosphonic acid,Zhao, X., Bell, J. G., Tang, S. F., Li, L., & Thomas, K. M, Journal of Materials Chemistry A,2016,4,4,1353-1365.
5.Ultrafine TiO2 Nanoparticles Confined in N-Doped Porous Carbon Networks as Anodes of High-Performance Sodium-Ion Batteries,Zhao, X., Yan, C., Gu, X., Li, L., Dai, P., Li, D., & Zhang, H, ChemElectroChem, 2017, 4, 6, 1516-1522.
1.Modulation of hydroxyl and nitrogenous group coadsorption induced by Ni and Cu doping on FeOOH for accelerating dehydrogenation in ammonia oxidation reaction. Shuo Zhang, Liting Yan, Huimin Jiang, Yanchao Zhao, Lingzhi Yang, Qiuju Fu, Enyan Guo, Jun Zhang, Xuebo Zhao*, Science China Materials, 2023.
2.Controllable Exfoliation of MOF-derived van der Waals Superstructure into Ultrathin Twodimensional B/N Co-doped Porous Carbon Nanosheets: A Superior Catalyst for Ambient Ammonia Electrosynthesis, Liting Yan, Yanchao Zhao, Shuo Zhang, Enyan Guo1, Cong Han, Huimin Jiang, Qiuju Fu, Lingzhi Yang, Weijing Niu, Yanlong Xing, Qiuju Zheng, Xuebo Zhao*,Small, 2023, 19, 202300239.
3. Self-Terminating Surface Reconstruction Induced by High-Index Facets of Delafossite for Accelerating Ammonia Oxidation Reaction Involving Lattice Oxygen. Shuo Zhang, Huimin Jiang, Liting Yan*, YanchaoZhao, Lingzhi Yang, Qiuju Fu, Dawei Li, Jun Zhang*, Xuebo Zhao*, Small, 2023,2207727.
4. Adsorption in Reversed Order of C2 Hydrocarbons on an Ultramicroporous Fluorinated Metal-Organic Framework. Lingzhi Yang, Liting Yan*, Weijing Niu, Yan Feng, Qiuju Fu, Shuo Zhang, Yinhang Zhang, Liangjun Li, Xin Gu, Pengcheng Dai, Dandan Liu, Qingbin Zheng*, Xuebo Zhao*, Angewandte Chemie International Edition, 2022, 61(25): e202204046.
5. Facile Fabrication of a Foamed Ag3CuS2 Film as an Efficient Self-Supporting Electrocatalyst for Ammonia Electrolysis Producing Hydrogen. Shuo Zhang, Liting Yan*, Huimin Jiang, Lingzhi Yang, YanchaoZhao, Xue Yang, Yameng Wang, Jianxing Shen, Xuebo Zhao*, ACS Applied Materials & Interfaces, 2022, 14(7): 9036–9045.
6. Boosting Fast and Stable Alkali Metal Ion Storage by Synergistic Engineering of Oxygen Vacancy and Amorphous Structure. Sheng Wen, Xin Gu*, Xiangwei Ding, Pengcheng Dai, Dongju Zhang, Liangjun Li, Dandan Liu, Xuebo Zhao*, and Jian Yang. Advanced Functional Materials, 2021, 2106751.
7. A CoSe-C@C core-shell structure with stable potassium storage performance realized by an effective solid electrolyte interphase layer. Xin Gu *, Li Zhang, Wenchao Zhang *, Sailin Liu, Sheng Wen, Xinning Mao, Pengcheng Dai, Liangjun Li, Dandan Liu, Xuebo Zhao * and Zaiping Guo. Journal of Material Chemical A, 2021, 9, 11397-11404.
8. Constructing ultrastable electrode/electrolyte interface for rapid potassium ion storage capability via salt chemistry and interfacial engineering. Sheng Wen, Xin Gu*, Xiangwei Ding, Li Zhang, Pengcheng Dai, Liangjun Li, Dandan Liu, Wenchao Zhang*, Xuebo Zhao*, and Zaiping Guo, Nano Research, 2021.
9. Boosting fast and stable potassium storage of iron selenide/carbon nanocomposites by electrolyte salt and solvent chemistry. Li Zhang, Xin Gu*, Xinning Mao, Sheng Wen, Pengcheng Dai, Liangjun Li, Dandan Liu, Xuebo Zhao*, Journal of Power Sources, 2021, 486, 229373.
10. Adsorption Site Selective Occupation Strategy within a MetalOrganic Framework for Highly Efficient Sieving Acetylene from Carbon Dioxide. Lingzhi Yang, Liting Yan, Ying Wang, Zhi Liu, Jiangxiu He, Qiuju Fu, Dandan Liu, Xin Gu, Pengcheng Dai, Liangjun Li and Xuebo Zhao*, Angewandte Chemie International Edition, 2021, 60, 4570-4574.
11. Electrochemical Surface Restructuring of Phosphorus Doped Carbon@MoP Electrocatalysts for Hydrogen Evolution. Huimin Jiang, Liting Yan*, Shuo Zhang, YanchaoZhao, Xue Yang, Yameng Wang, Jianxing Shen, Xuebo Zhao*, and Lianzhou Wang*, Nano-Micro Letters, 2021, 13 (1): 215.
12. Spherical Superstructure of Boron Nitride Nanosheets Derived from Boron-Containing Metal−Organic Frameworks, Lei Cao, Pengcheng Dai,* Jing Tang, Dong Li, Ruihua Chen, Dandan Liu, Xin Gu, Liangjun Li, Yoshio Bando, Yong Sik Ok, Xuebo Zhao,* and Yusuke Yamauchi*, Journal of the American Chemical Society, 2020, 142, 8755−8762.
13. Graphitic carbon nitride catalyzes selective oxidative dehydrogenation of propane. Lei Cao, Pengcheng Dai*, Lei Zhu,*, Liting Yan, Ruihua Chen, Dandan Liu, Xin Gu, Liangjun Li, Qingzhong Xue, Xuebo Zhao,*Applied Catalysis B: Environmental, 2020, 262, 118277.
14. A Freestanding 3D Heterostructure Film Stitched by MOF-derived Carbon Nanotube Microsphere Superstructure and Reduced Graphene Oxide Sheets: A Superior Multifunctional Electrode for Overall Water Splitting and Zn-Air Batteries. Liting Yan*, Yulin Xu, Pan Chen, Shuo Zhang, Huimin Jiang, Lingzhi Yang, Ying Wang, Li Zhang, Jianxing Shen*, Xuebo Zhao*, and Lianzhou Wang*, Advanced Materials, 2020, 32 (48): 2003313.
15. Sustained-Release Method for the Directed Synthesis of ZIF-Derived Ultrafine Co-N C ORR Catalysts with Embedded Co Quantum Dots. Han Ye, Liangjun Li,* Dandan Liu, Qiuju Fu, Fuzhao Zhang, Pengcheng Dai, Xin Gu, and Xuebo Zhao*, ACS Applied Materials & Interfaces, 2020, 12, 57847−57858.
16. Superstructure of a Metal-Organic Framework Derived from Microdroplet Flow Reaction: An Intermediate State of Crystallization by Particle Attachment,Ying, Wang,Li, Liangjun*;Liang, Huimin;Xing, Yanlong;Yan, Liting;Dai, Pengcheng;Gu, Xin;Zhao, Guoming;Zhao, Xuebo*; ACS Nano, 2019, 13, 2901-2912.
17. Metal-organic frameworks: a promising platform of constructing non-noble electrocatalysts for oxygen-reduction reaction,Liangjun Li, Jiangxiu He, Ying Wang, Xiaoxia Lv, Xin Gu, Pengcheng Dai, Dandan Liu, Xuebo Zhao*,Journal of Materials Chemistry A,2019,DOI: 10.1039/C8TA11704G.
18. Titanosilicate Derived SiO2/TiO2@C Nanosheets with Highly Distributed TiO2 Nanoparticles in SiO2 Matrix as Robust Lithium Ion Battery Anode, Li Zhang, Xin Gu, Chunliu Yan, Shuo Zhang, Liangjun Li, Yingjie Jin, Shanlin Zhao, Haiyan Wang, and Xuebo Zhao*. ACS Applied Materials & Interfaces, 2018, 10(51): 44463–44471.
19. Paper-Derived Flexible 3D Interconnected Carbon Microfiber Networks with Controllable Pore Sizes for Supercapacitors, Dai, Pengcheng; Xue, Yanming; Zhang, Shuo; Cao, Lei; Zhao, Xuebo*,ACS applied materials & interfaces,2018,10 ,43, 37046-37056.
20. Highly dispersed Zn nanoparticles confined in nanoporous carbon network: promising anode materials for sodium and potassium ion batteries, Chunliu Yan, Xin Gu, Li Zhang, ying wang, Liting Yan, Dandan Liu, Liangjun Li, Pengcheng Dai and Xuebo Zhao*, J. Mater. Chem. A, 2018, 6, 17371-17377.
21. Bottom-Up Fabrication of Ultrathin 2D Zr Metal-Organic Framework Nanosheets through a Facile Continuous Microdroplet Flow Reaction,Wang, Y; Li, LJ; Yan, LT; Gu, X; Dai, PC; Liu, DD; Bell, JG; Zhao, GM; Zhao, XB* ; Thomas, KM*;Chemistry of Materials,2018,30,9: 3048-3059.
22. Nickel metal-organic framework implanted on graphene and incubated to be ultrasmall nickel phosphide nanocrystals acts as a highly efficient water splitting electrocatalyst,Yan, LT ; Jiang, HM; Xing, YL; Wang, Y; Liu, DD ; Gu, X; Dai, PC ; Li, LJ;Zhao, XB*,Journal of Materials Chemistry A,2018, 6, 4,1682-1691.
23. Carbonates (bicarbonates)/reduced graphene oxide as anode materials for sodium-ion batteries,Gu, X ; Yan, CL; Yan, LT; Cao, L ; Niu, FE; Liu, DD ; Dai, PC ; Li, LJ; Yang, J ; Zhao, XB*,Journal of Materials Chemistry A,2017,5,47,24645-24650.
24. Missing-node directed synthesis of hierarchical pores on a zirconium metal-organic framework with tunable porosity and enhanced surface acidity via a microdroplet flow reaction,Wang, Y; Li, LJ; Dai, PC ; Yan, LT; Cao, L ; Gu, X; Zhao, XB*,Journal of Materials Chemistry A,2017,5, 42,22372-22379.
25. Metal-Organic Frameworks Derived Nanotube of Nickel-Cobalt Bimetal Phosphides as Highly Efficient Electrocatalysts for Overall Water Splitting, Yan, LT ; Cao, L ; Dai, PC; Gu, X; Liu, DD; Li, LJ; Wang, Y ; Zhao, XB*,Advanced Functional Materials,2017,27,40,1703455.
26. Exceptional high selectivity of hydrogen/methane separation on a phosphonate-based MOF membrane with exclusion of methane molecules, Yang, QP ; Li, LJ; Tan, WQ ; Sun, YJ; Wang, HL; Ma, JP ; Zhao, XB* , Chemical Communications, 2017,53, 70, 9797-9800.
27. High efficiency organic solar cells based on amorphous electron-donating polymer and modified fullerene acceptor, Xiao, B; Zhang, ML; Yan, J ; Luo, GP ; Gao, K ; Liu, JY ; You, QL ; Wang, HB ; Gao, C; Zhao, BF ; Zhao, XB*; Wu, HB ; Liu, F , Nano Energy, 2017, 39, 478-488.
28. High Oxygen Reduction Activity on a Metal-Organic Framework derived Carbon Combined with High Degree of Graphitization and Pyridinic-N Dopants. Li, L., P. Dai, X. Gu, Y. Wang, L. Yan and X. Zhao*. Journal of Materials Chemistry A,2017, 5: 789-795.
29. In Situ Synthesis Strategy for Hierarchically Porous Ni2P Polyhedrons from MOFs Templates with Enhanced Electrochemical Properties for Hydrogen Evolution. Liting Yan, Pengcheng Dai, Ying Wang, Xin Gu, Liangjun Li, Lei Cao, and Xuebo Zhao*, ACS Appl. Mater. Interfaces, 2017, 9 (13), 11642–11650.
30. Coaxial MnO/N-doped carbon nanorods for advanced lithium-ion battery anodes. Xin Gu, Jie Yue, Liang Chen, Shuo Liu, Huayun Xu, Jian Yang *, Yitai Qian * and Xuebo Zhao*. J. Mater. Chem. A, 2015, 3, 1037-1041.
31. Solvothermal Metal Metathesis on a Metal Organic Framework with Constricted Pores and the Study of Gas Separation. Liangjun Li, Haitao Xue, Ying Wang, Pinhui Zhao, Dandan Zhu, Min Jiang, and Xuebo Zhao*,ACS Appl. Mater. Interfaces,2015, 7(45), 25402-25412.
32. Hysteretic Gas and Vapor Sorption in Flexible Interpenetrated Lanthanide-Based Metal–Organic Frameworks with Coordinated Molecular Gating via Reversible Single-Crystal-to-Single-Crystal Transformation for Enhanced Selectivity. Chao Wang, Liangjun Li, Jon G. Bell, Xiaoxia Lv, Sifu Tang, Xuebo Zhao*, and K. Mark Thomas*. Chem. Mater., 2015, 27 (5), 1502–1516.
33. High CO2/N2 and CO2/CH4 selectivity in a chiral metal-organic framework with contracted pores and multiple functionalities, Xiaoxia Lv, Liangjun Li, Sifu Tang, Jinjun Cai, Xuebo Zhao*, Chem. Commun., 2014, 50, 6886-6889.
34. Enhanced uptake and selectivity of CO2 adsorption in a hydrostable metal-organic frameworks via incorporating methylol and methyl groups, Chao Wang, Liangjun Li, Sifu Tang and Xuebo Zhao*, ACS Appl. Mater. Interfaces, 2014, 6(19), 16932–16940.
35. Gas Storage and Diffusion through Nano-Cages and Windows in Porous Metal Organic Framework Cu2(2,3,5,6-tetramethylbenzene-1,4-diisophthalate)(H2O)2, Liangjun Li, Sifu Tang, Jon G Bell, Xiaoxia Lv, Xianrui Xu, Yanlong Xing, Xuebo Zhao*, Mark Thomas*, Chemistry of Materials, 2014, 26 (16), 4679–4695.
36. Nitrogen-doped porous carbons from bipyridine-based metal-organic frameworks: Electrocatalysis for oxygen reduction reaction and Pt-catalyst support for methanol electrooxidation, Dandan Zhu, Lianglun Li, Jinjun Cai, Xiaoxia Lv, Min Jiang, Xuebo Zhao*, Carbon, 2014, 79, 544-553.
37. Poly(vinylidene chloride)-based carbon with ultrahigh microporosity and outstanding performance for CO2 capture and H2 storage,Jinjun Cai, Jingbo Qi, Chunpeng Yang, Xuebo Zhao*,ACS Applied Materials & Interfaces,2014,6, 3703−3711.
38. Electrolysis of ammonia for Hydrogen Production Catalyzed by Pt and Pt-Ir Depositied on Nickel Foam, Ming Jiang, Dandan Zhu, Xuebo Zhao*, Journal of Energy Chemistry, 2014, 23,1-8.
39. High gas storage capacities and stepwise adsorption in a UiO type metal-organic framework incorporating Lewis basic bipyridyl sites,Liangjun Li, Sifu Tang, Chao Wang, Xiaoxia Lv, Min Jiang, Huaizhi Wu, Xuebo Zhao*,ChemComm,2014,50, 2304-2307.
40. Large Surface Area Ordered Porous Carbons via Nanocasting Zeolite 10X and High Performance for Hydrogen Storage Application, Jinjun Cai, Liangjun Li, Xiaoxia Lv, Chunpeng Yang, Xuebo Zhao*, ACS Applied Materials & Interfaces, 2014, 6,167-175.
代表性合作论文:
1、High H2 Adsorption by Coordination-Framework Materials, Angewandte Chemie International Edition, 2006, 45, 7358-7364.
2、High-capacity hydrogen and nitric oxide adsorption and storage in a metal-organic framework. Journal of the American Chemical Society, 2007, 129(5): 1203-1209.
3、Surface interactions and quantum kinetic molecular sieving for H-2 and D-2 adsorption on a mixed metal-organic framework material, Journal of the American Chemical Society, 2008, 130(20): 6411-6423
4、Rationally tuned micropores within enantiopure metal-organic frameworks for highly selective separation of acetylene and ethylene,Nature Communications, 2011, 2(1): 204
5、Chemically Blockable Transformation and Ultra-selective Low Pressure Gas Adsorption in a Metal Organic Framework, Nature chemistry, 2009, 1(4): 289-294.
授权专利:
1.一种碳分子筛的制备方法
2.超细M-N-C非贵金属碳基氧还原催化剂、制备方法及应用
3.一种低温制备三维梯级孔结构的Ni2P催化剂的方法
4.一种过渡金属修饰的氧化还原催化剂及其制备方法
5.一种磷化钼催化剂及其制备方法
6.一种钠离子电池负极用碳酸钴/石墨烯复合材料及其制备方法与应用
7.一种梯级孔结构的金属有机框架化合物的连续合成方法
8.一种氮化硼/氧化镍复合材料及其制备方法与应用
9.一种钠离子电池负极用碳酸亚铁/石墨烯复合材料及其制备方法与应用
10.重油催化裂化再生剂输送管路取热方法
11.一种高性能钾离子电池负极用硒化钴
12.一种在超临界溶剂中渣油催化裂化方法
13.一种三维多孔碳纳米管石墨烯复合膜及其制备方法
14.一种催化中心均匀分布的多金属磷化物纳米管催化剂及低温制备方法
15.一种新型磷化镍催化剂及其制备方法
16.一种钠离子电池负极用碳酸氢镍/石墨烯复合材料及其制备方法与应用
17.一种膦酸盐类金属有机框架化合物及制法和应用
18.一种多级孔金属-有机框架气相色谱固定相材料的制备方法
19.一种有机胺阳离子修饰的金属-有机框架材料及其制备方法
20.一种海绵结构γ-Al2O3材料及其制备方法